m0useanswered grow question a year ago Is your diaries information accurate?
I'd aim to give them plants some sleep. 20/4 is the maximum I would do for its light cycle AKA its photoperiod and I would only do this for a shot span of time. Ideally 18/6 is better suited to my need and light strength for any autos seed-harvest or vegging photoperiods.
time on/off does not matter as much as DLI does. You can give a DLI of 40 in 12/12 cycle or in 18/6 cycle depending on lights strength and dimming capabilities. Its what counts towards good proper growth, to much light may result in a higher then normal DLI and excess is not better.
I have not seen the first pics leafs symptoms before, it makes me wonder if it was something in the environment as its only on two of the finger on one leaf and nowhere else on the plant. The 2nd pic looks to be like it may be wanting some potassium. I would check your feeding ratios and confirm if it is lacking or not. I don't see what your feeding in your diary, best to update that.
Last point is PH. 6,7 is ok but I would aim for that to be aorund 6,4-6,5 in soil. just a small decrease, nothing crazy probably won't matter but that's my preference.
Good Luck!