purple petioles might be p-deficiency, but also simply just happen with some plants. LED may exacerbate it too.
i've tried on numerous grows to avoid it. nothing really works. More p? more mg? nope.
I don't see a p-deficiency here, either. leaves get a blueish hue and progreseses into dead spots on lower leaves. I don't think your purple petioles are related to p-deficiency without other symptoms.