Hey, sorry the response will be a bit long. The hypothesis about Rhizotonic: It's very likely. Organic additives or root boosters like Rhizotonic often stain the roots brown/blackish, especially on the upper part that isn't constantly submerged but sprayed by the bubbles. If the roots are firm and don't slip between your fingers, it's probably just a coloration.
The temperature (19°C): At 19°C, you're in the perfect safety zone. Pythium (root rot) has a hard time developing below 21-22°C. So, on this point, I'm pretty calm.
Oxygen: The fact that it's foaming a bit shows that your air stones are doing their job. However, if the foam is too thick, it can sometimes smother the base of the roots a bit.
What I'm going to check to be sure:
The smell: This is the ultimate test. If it smells like fresh soil or nothing at all, it's Rhizotonic. If it smells like swamp or rotten potato, it's a bacterial infection.
The texture: I'm going to touch the dark roots. If they're solid, that's good. If they stay in my hands or are slimy, it's the beginning of root rot.
The tips of the roots: If the tips of the roots (lower in the water) are white and healthy, then the black coloration at the top is indeed due to the product deposit. I hope I could help you, have a good evening.