Yes and no. 2 plants may use the light more efficiently because they are closer to the center of the coverage area and receiving the proper ppfd. This advantage is minimal though, as you can adjust your light height down, giving them more ppfd. The only issue is if you lose coverage by lowering the light too much.
Plants may compete for light though if they're close together. I originally did 4 plants in my tent and it got so crowded I went with just 2 this time. I'm expecting 25% less yield, but a much better final product.
Hope this helps you a bit!