vpd is an equation of vapor pressure inside plant / just outside stomata.
if you have an infrared thermometer you'd want to take measurements of the leaves. The stomata are on the underside. Reference that with a VPD table.
23-26C
@70% RH is .8ish to 1ish... depending on where you look you may see suggestions in this range or even a bit higher for early vege.
Without a solid source and suggestions you can be confident about, they can be a good ballpark. Measuring these things and keeping track of it helps. You can test out a particular vpd for several grows to build a baseline across various growth patterns and then try something new and compare. without a baseline it's like a chicken running around with its head cut off.
I don't take measurements at leaf, but my measurements are consistently made - i.e. probe is in the same spot, good circulation keeps climate consistent throughout tent. My vpd is lower than what i typically see on my phone app, but it's lower in a similar way each time. While i shouldn't suggest the VPDs i use, i can do the same trial and error as long as the offset (leaf vs air temps) remains consistent. you can subtract 3-5F if you want, but still not precise as an infrared taking leaf temp. The point is, it can still be useful even if you don't have the "exact" VPD.
I mostly just avoid problematic VPD -- too high/too low is bad. I've read you want no more than a 0.4 difference from dark/light cycles. I'd prefer the 'right' vpd with temps that keep me in 40-65% RH range... higher RH% for seedlinges is fine. The key there is it is short-term. Air out humidity domes religiously. 40-65% avoids higher risk of microbial growth. Should be able to stay within suggested VPD ranges for all phases and be within this range.
Google image search a vapor pressure deficit table -- take a peak at a few and see the range of suggestions just to get an idea. The better ones will color code it for too much and fungal/microbial risks.
avoid dew point. When you have higher RH and higher temps, when those lights go off the temps drop and RH can skyrocket. Look up dewpoint of your peak lights on temp/rh and make sure you don't get near it at lights out. If ever around 30+C/50-65%, you start seeing dewpoints that are easy to hit.