low N that has advanced beyond chlorosis, or you've inhibited it's availability with recent formula change or pH swing. Could also just be the plant shedding a lower, shielded leaf. common sense should allow you to eliminate the possibilities.
it's a myth that boosting p or k in flower increases yield or potency. If avoiding toxicities and deficiencies, you are in a good spot. Amping up and causing a toxicity does no good. if a toxicity does show up, it's evidence that the plant is receiving WAY more than it can use, which obviously doesn't help to treat it like foie gras.