Rain water is a great way to introduce heavy metals and other very common pollutants to your plants, lol.
ppm converted from EC is not to be trusted. There are 4-5 different conversion factors that different manufacturer's use, which should be explanation enough as to why it's a trash conversion.
also, shit or get off the pot as far as bottom or top feed. just keep it simple instead of trying to be overly sophisticated and extra effort with no return on investment. Top-down feeding is superior because it has less risk of buildup, especially if in soilless substrate where the 10% runoff is essential to maintaining an equilibrium concentration of nutrients.
flushing should be reserved for extreme catastrophes. you can usually fix problems without a flush. Should avoid it as much as possible because it's a pretty big negative impact for the plant.
with all the flip-flopping and sophistry, it'd be pretty hard to diagnose at this point. Your own behaviour trying to fix it could be as much of a causal factor as the original reason.
could be micros - deficient or inhibited.
K-tox possible, too, which if you recently boosted K, makes it more likely.
You sure that rain is consistently a 7 pH, that's be incredibly unusual, lol.
The good thing is it looks minor and slow moving. you can be patient instead of throwing kerosene on a fire with early guesses. Find enough cross-reference information to make a more informed choice. you can be patient.