is a toxicity building up?
Restricting building blocks will never result in bigger buds, assuming you are not overdosing it.
yes, your leaves have stored nutrients and will sustain a plant if you do. it's fine to be lazy, but don'tlie to yourself about it somehow magiclaly improving quality or yield.
it's not about "more." it's about maintaining levels around the roots that meet needs of the plant. you cannot force feed it. it is not foie gras. this s about concentration around roots that are sufficeint and don't lockout other nutrients.. .and vice verse for all other nute molecules.
studies show going over 190ug/L doesn't result in anything measurably different. There may be genetic variety or environmental factors that shift exactly what this is in your garden, but it clearly shows that just loading up on "more" of it is only going to flush a shit tone of excess, unused P/K down the drain.
A significant portion of P/K intake is done through active transport and not simple diffusion across a membrane on root. The plant sends out carrier molecules to bond with specific p/k molecules and re-enter. there are feedback loops to control these processes. The plant actively grabs p and k on demand rather than mass flow intake (some does enter through basic diffusion, too).
the right amount is the goal. Trial and error will get you there. Any toxicity arises tells you that you provided too much leading up to that point -- whether it takes days, weeks or months to occur, it is still true. If deficiencies arise, that tells you that you did not provide enough leading up to that point. So, you find an upper threshold and dial back. this probably resutls in some waste, but ensures you are not shorting the plant in any way.
any change in overall formula can impact the uptake of other molecules, so if the formula changes, you may need to tweak other things. Increasing Ca may impede availability of some other nutes.. then those nutes also have to be increase to mitigate it, which can aldo domino into impacting uptake of even more elements, lol... it is simple but complicated.
drastically shifting the formula is more akin to masturbation. a 20-30% drop of N as you go into flower is probably the only thing you should be shifting significantly. Any excess p/k you feed in vege that doesn't cauase a toxicity will be stored for use later -- not saying thise hypothesis is correct, but the fact you don't get deficiencies or run into toxicities is the proof of how it was supplied/used in proper amounts. if youload it up with a particular nute and end up with a fried canopy, have some humility and accept that your behaviour caused it.