The leaf damage looks more like potassium deficiency (K) than phosphorus or calcium the rusty, burned edges are typical for K issues. Phosphorus usually shows darker/purplish tones, and calcium more spotty necrosis. With pH at 6.7 you’re on the upper end, so nutrient uptake might already be limited. Personally, I always keep it around 6.0–6.3 max for better balance. Since K, Ca, and Mg are often hard to tell apart and interact with each other, I’d supply all three components together instead of guessing just one. No need to flush unless you’ve overfed better to adjust feedings and ensure a steady base instead of only using Big Bud