18h and ~600ppfd should be fine.. but if it needs 5-15% less, that's possible, too.. it's a good spot to start. 400ppfd (if accurately measured) is probably lower than necessary.
12h you want 800-900ppfd. You need to reference DLI. DLI is what matters. PPFD without hours of operation is half useless.
PPFD is not a single point measurement. So if you or an app is calculating it from a single measurement, it's not likely an accurate value. Also, phones merely convert lux using a conversion factor that may or may not be entirely accurate. It'll depend on the spectrum flux and how it varies from whatever they decided was an average grow light spectrum.
Flushing is pretty stressful and should be avoided as best you can, not turned to as a fix-all for minor issues.
based on any leaf chart, yellwing inside-out on top leaves could be S-deficiency. Looks minor. If it fills in quickly, may not even be a problem.
Other things can also cause chlorosis and skinny leaves in new growth -- too much p or k, if you boosted it recently is a potential cause, too.
leaf symptoms are not discrete. you will have to use more information to eliminate possibiities and make a common sense decision on what to try first. I also see it on the 2nd level of leaves under the top, so i doubt it's light-related. I'd wager a slight boost to S concentration while maintaining other levels of nutrients would solve this problem. Since it's a small issue, i would not make a drastic change to S, though. Start small... can incrementally increase it.
This stuff takes time. don't expect immediate results overnight. The rate at which it is progressing is the key.. if it regresses, you know you've course corrected, but then keep an eye out for going too far the other way... rates of change over time and trying to find that equilibrium with environment is a matter of trial and error.