Wouldn't worry to much as the 1st set of leaves always does this but I agree with the others, check your PH and ppms religiously, for me after I mix my nutes my ph always rises by 0.6 after a couple hours once oxygenated by the airstones, it then becomes stable. Make sure you always store your PH meter correctly in storage solution and calibrate it regularly.
Also make sure you have Calmag as will be essential in DWC under led's, personally I start adding after 2 weeks for the remainder of the grow.