1stly.
You can PH water that runs off from soil
U need a soil ph meter.
This method can only be applied with coco..
As with soil nutrients are taken in different and oh its just too long to explain.
U just can't ph like that.
The ph solution you're putting in works as you say. So, if there was issues, you'd of seen them by now
And BTW, you shouldn't be wetting the soil enough to get run off.
Good luck.