Heya, Its's pre-amended soil, meaning it got all the nutrients it needs for that grow already in the soil(Organic), you were 2 weeks into flower, so it is very possible what you were seeing was actually the reallocation of nitrogen to other parts of the plant, and not a nitrogen deficiency at all, it is a process called Senescence. When you buy buckets like that its carefully measured because in a perfect grow you actually want nitrogen to be depleted from the medium sometime during flower as N and K both share the biggest highways within the stems for nutrient transport, this way the plant will eat up all of its excess nitrogen(green) in the end this means less chlorophyll in your plant come cure time, but most importantly is responsible for other colors shine through like the anthocyanin or carotenoids.
You do not want to add concentrates to organic grows either as it wipes out eco system, and unless you know what kind of nitrogen your mixing together as anything over 30% ammoniacal nitrogen can cause PH TO GO WILD.
When you flushed, you flushed everything else out the plant entirely.
8ph water means its high in salt, what is salt but salt minerals, calcium, potassium, magnesium, Plant is ssucking all the salt minerals and nutrients from water leaving your runoff acidic.
Honestly if you want to save her grab a small bag of "NPK RAW BLOOM" use 1"8th tsp every other watering, all she needs and way more.
Breaking Down Nitrogen Forms & Their Impact:
Forms of Nitrogen:
Nitrogen, comes in three primary forms: ammonium, nitrate, and urea. Ammonium (NH4+) carries a positive charge, nitrate (NH3–)carries a negative charge, while urea ((NH2)2CO) carries no charge.
Natural Processes in Media:
Once these nitrogen forms are introduced into the growing media, natural processes kick in. Bacteria play a vital role, converting urea to ammonium or ammonium to nitrate. This latter conversion releases hydrogen ions, increasing media acidity.
Urea Conversion:
Urea undergoes rapid conversion to ammonium in the soil, usually within two days. Both urea and ammonium are often grouped together and referred to as ammoniacal nitrogen.
When plants absorb nitrogen, they typically release a molecule with the same charge to maintain internal pH. This process can also alter the pH of the media surrounding the roots.
pH Effects of Nitrogen Uptake:
Ammonium (NO4) Uptake and pH:
When plants absorb ammonium, they release hydrogen ions (H+) into the media. This increases the acidity of the media over time, decreasing the pH.
Nitrate (NO3) Uptake and pH:
Plants take up nitrate by releasing hydroxide ions (OH–). These ions combine with hydrogen ions to form water. The reduction in hydrogen ions eventually reduces the media acidity increasing the pH.
Nitrate (NO3) Absorption Variations:
Sometimes, plants absorb nitrate differently, either by taking in hydrogen ions or releasing bicarbonate. Like hydroxide ions, bicarbonate reacts with hydrogen ions and indirectly raises the media pH.
Understanding these processes helps in choosing the appropriate fertilizer to manage media pH. Depending on the nutrients present, the media’s acidity or alkalinity can be adjusted to optimize plant growth.
Risks of Ammoniacal Nitrogen:
Plants can only absorb a certain amount of nitrogen at a time. However, they have the ability to store excess nitrogen for later use if needed.
Nitrate (NO3) vs. Ammonium (NH4):
Plants can safely store nitrate, but too much ammonium can harm cells. Thankfully, bacteria in the media convert urea and ammonium to nitrate, reducing the risk of ammonium buildup.
Factors Affecting Ammonium (NH4) Levels:
Certain conditions like low temperatures, waterlogged media, and low pH can prevent bacteria from converting ammonium. This can lead to toxic levels of ammonium in the media, causing damage to plant cells.
Symptoms of Ammonium (NH4) Toxicity:
Upward or downward curling of lower leaves depending on plant species; and yellowing between the veins of older leaves which can progress to cell death.
Preventing Ammonium (NH4) Toxicity:
When it comes to nitrogen breakdown of a nutrient solution, it’s crucial not to exceed 30% of the total nitrogen as ammoniacal nitrogen. Higher levels can lead to toxicity, severe damage, and even plant death.
Ideal Nitrogen Ratio for Cannabis:
Best Nitrogen (NO3) Ratio:
Research shows that medical cannabis plants respond best to nitrogen supplied in the form of nitrate (NO3). This helps them produce more flowers and maintain healthy levels of secondary compounds.
Safe Ammonium (NH4) Levels:
While high levels of ammonium (NH4) can be harmful to cannabis plants, moderate levels (around 10-30% of the total nitrogen) are are considered most suitable. This level helps prevent leaf burn and pH changes in the media.
Good luck.