Hi mate, you may be having a few thing going on. Calcium and magnesium deficiency as well as low oxygen in root zone. You may be experiencing a lock out which is causing the Ca and Mg deficiency. usually caused by ph problems. A very small amount of hydrogen peroxide will add more oxygen to you soil when watering and just keep an eye on the temp of the water. Should be between 67/72'F. I Hope this helps, good luck and happy growing.