This happens on my Apera from time to time... if it stays there, just accept it and go on to calibrate at the 10pH ... it will be just fine! I think what's happening is that the pen is telling itself "gee, I've been reading the 4pH too high" so the OLD 4.5 reading will now be the NEW 4.0 reading...
You can always call Blue Lab and double check - but I think you'll find it's nothing to worry about.
Cheers!