Nutrients have a shelf life of 2-3yrs upon opening.
If you set your PH at 5. It'll give you more of a window before you have to adjust.
If your plant is having difficulty taking in the likes of mag. You can give a foliar spray. I use 250ppm (110ppm ambient tap) so whatever yours is, add a 100-150 to your value and spray the leafs off your girl every 2 days until you see a change. "Be sure if you've strong lights, to turn them down, the leafs will dry up within 30m"
You can also add Epsom Salt to your Hydro water. Most ppl tend to jst use a cal mag. I like to use either a cal powder r mag for either issue. It helps the plant just focus on sole nute.
It is down to your PH as the sides that are sticking up, are early signs of PH imbalance.