I might have found the Problem wich was cousing the Brown Spots. I had a Red/FarRed (660nm) light next to my LED grow light hanging, at the same Hight (35cm). After seeing this vid :
www.youtube.com/watch
I wanten to See of the red light coused the Problem and Shut it down the last 2 days. Now the Newer bigger leaves dont tend to Brown anymore. Lets See in the next few days is this realy was the case.
But i will switch to Another nutriënt as wel to get my PH more stable.
Thanks