If you have a good nutrient schedule, this could just be natural colouration and there are no issues, I see this very often. If this is the only symptom I wouldn't be concerned. When there is a deficiency, purple leaf stem (petioles) is a sign of phosphorus deficiency but I'd also look for other symptoms, dark green almost blue leaves or brown leaves and slow / stunted growth. If you have a few of these symptoms then correct with more phosphorus. In the veg stage you need 30ppm of Phos. In flower you need 120 ppm Phos. in hydroponic / coco grows. hope this helps.