The pH of rainwater fluctuates, but most rainwater in the U.S. tends to be substantially lower than 8. Average pH of rainwater tends to run in the 5’s and 6’s. As CO2 levels in the atmosphere continue to rise, we can expect the pH of rainwater to become even more acidic, thus more acid rain. If you’re collecting rainwater in a 55-gallon drum, add your nutrients, then adjust the pH (using pH up or down) to optimal levels before watering your plants.
Hope this helps! Happy growing!