This kind of damage in the first leave is a P deficiency, in the 2nd one you can see excess of N; the leaves can go down for so many factors, root damage, excess of water (I can see leaves with thicken cell walls) high temperature with low humidity..
I'll reduce biogrow to 0.5ml*L for a few weeks and see how it goes, check how much and how frecuently you water your plants and keep going.