That looks like a calcium deficiency. I'm not sure why you would encounter that in soil, but it can happen. Have you watered until runoff and tested the ph of that? Maybe your mediums ph is a bit out of whack? If not You might just want to add a little calmag to your feedings. If its only 1 leaf, I might not really worry about it too much yet. Hell, I had a plant with a really bad calcium deficiency towards the end of flower due to me using a dechlorinator and it causing calcium to be unavailable. That plant still wound up having a great harvest with nice buds, the leaves just looked ugly as hell. So maybe give it another 3-5 days and see if it gets much worse? If it does and your ph is solid then add a little calmag or another form of calcium.