BioBizz nutrients do not do well below a PH of 6.2, giving your going in at 6 I would bump that up.
Also not all nutrient brands are interchangeable, some of them might reacted with each other and lock out things in the medium.
This to me looks like a calcium issue and I bet its caused by a lock out of to many fertilizers in the medium. Your going in a 1.4ec with a lot of products.
Autos like to lightly feed compared to there photoperiod counterparts.
https://www.autoflower.net/forums/threads/med-man-method-feeding-chart-ppm-ec.47856/
This is a great reference point for auto feeding, it needs to be noted it is not universal but a great start.
I would also look at monitoring your runoff EC if you are getting any. This will let you know how much the plants need. If the ec is higher in the run off its getting to much,. The EC and PH values will have a small effect on each other as well. lower ec raises PH and higher EC will lower the PH..typically.
Best Of Luck!
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