First off that 100W light is not hurting things at 15”..
The specs from manufacturer (which are likely inflated if anything ) show at 14” your peak PPFD in the center at 750 umols/m2/sec , with an average across the canopy being more like 600ish likely.
To answer the question about mag deficiency. Yes you have SIGNS of it, with the interveinal chlorosis beginning slightly. That is a common symptom of magnesium deficiency.