Check roots for root problem. This is the most common thing in hydro and will trigger nutrient defeciency like brown spots and burning of the tips etc... I personally recommend using a supplement called Botanicare Hydroguard for root problems because I’ve used it successfully to get rid of a terrible case of Root Rot. If you are sure it's calcium defeciency in hydro, calcium is best absorbed by the roots in the 6.2 – 6.5 pH range (in hydro, it’s generally recommended to keep the pH between 5.5 – 6.5, but calcium specifically tends to be best absorbed above 6.2)