this is just unavoidable with LED... may not h appen with all plants but will happen. if oyu see it with all plants, it may be worth a little trial and error. If just on top, another sign it's nothing you can really do anything about. Whether it is LED or some other cause i don't know. Red petioles can come from low P. Low S causes red streaks in stems, not petioles. So, try boosting P, but it's never worked for me.