in the first week i wouldn't feed them anything.. they should still have enough nutrients from the seed.
If you want to feed them, then only a tiny amount (best if you have an EC meter to measure it).
The question whether you want to add cal/mag is more about the type of water that you use.. If you have hard tap-water there might be a lot of salts already included.
That's why many people (me included) use reverse osmosis water (the RO filter cost me about 50 bucks and 15 for an adapter to my tap). This will remove all the salts and bring the EC value down to 0. In that case it's necessary to add calcium and magnesium back, and that's when the calmag needs to be added.
When using tap-water i'd only add it if i see a deficiency.
If you're on soil, i also recommend reading this link: https://www.mandalaseeds.com/Guides/Fertilizing-Smart-Guide
Has helped me a lot in the beginning.
happy growing!