could be a P tox? I see some dots, which look like Ca from lockout, and the necrotic tip.
you added ca.. it's progressing? it's likely lockout, if you have been fertilizing regularly.
if you've been light on fertilization, then pick it up and see what happens.
yellowing of lower leaves too... nitro typically, but can be other things and not just deficiencies.. k-tox can cause that.