Two ways.
Easiest but not accurate: wait until 90-100% of the hairs have turned red and begun receding back into the flowers.
Better way: use a jeweler's loupe or magnifying glass to look at the trichomes.
10% Amber is your highest THC content, psychedelic head high
20% Amber is a nice head high with some relaxation effects
30% Amber is a healthy mix.
50-70% Amber heavy body high, couchlock, munchies, sleep aid
Over 70% Amber you've waited a bit too long, this will knock you out