hey there you have all the symptoms of phosphorous deficiency . purple stems , copper colored splotches, some dark and brown spots, mottling patterns , leaf tips affected, yep, that P deficiency ! you're going pretty light on the nutes as it is, but doing everything right including foliar spray which is good. you can probably double the diamond nectar which is mag sulfur, and flora bloom which is P/K no problem. to get the juices flowing consider a chelation agent, but it's optional. as long as you up the P/K the problem should stop spreading. Hope this helps ! 🚀