Dropping temperatures at night will do it, but its generally regarded as sacrificing potency for looks. If it has the genes, it will likely purple without the temp drop anyway. This generally happens in the last two weeks anyway. The temp drop is also though to produce more terpenes, giving your bud a better taste, but this is mostly unproven.
In the end, I'm not sure it's worth it unless you really want the extra "bag appeal".