One spot is not the end of the world, no plant will ever have 100% perfect leaves, 100% of the time.
Definite burning though from too much feeding, half strength is usually plenty strong enough.
I would also be dropping the baking soda (too alkaline) and reducing the application of hydroguard to once evey 14 days.
Remember too, what is now showing in the leaves is what occurred in the substrate 10-14 days ago, so expect a delay in what you are giving to when you see results, but upping the cal/mag/iron won't hurt, especially in a soil-less grow.
Cheers, Organoman.