First of all, if you're new to growing, you should start a diary here... Diaries are why this site exists! And without them, you can't track your grows and we can't figure out what you've done or not done that might be the cause of problems. Additional information that's quite important is how old the plant is, what kind (auto or photo), humidity, EC....
You're basically showing us a picture of a leaf that looks pretty sad - but I'd really like to see the whole plant... or at least more of it. It looks like it's one of the very first leaves and if they are the only ones showing this problem, I don't think I'd be very concerned... I'd be more concerned if the same sort of discoloration was showing on the leaves above it...
You're not telling us what nutes you're using, and in what amounts... VERY important here... Your pH is spot on, so that's not a problem at all.... 68F for your water is a bit too warm, I'd get it down to 62F max...
The leaves look, for all the world, like you've got a potassium deficiency starting but that usually doesn't occur on the lowest leaves first... so basically, what I'm saying is that we need a lot more information... We WANT to help - but we need info in order to have a rational basis for our advice...