Manganese is an inert mineral. Therefore, any deficiency will initially affect the newly formed leaves. The growth of new shoots will be significantly slowed down. Young leaves will start to yellow and develop brown spots.
In the diary, I looked at what you use as fertilizers, and it seems like you're hardly giving any, so the deficiency could be of various elements.
I would start giving something with macronutrients and micronutrients, so a complete fertilizer.
The calcium deficiency, as I mentioned, is minimal, but a dose will just tickle it; you need to wait at least a couple of waterings.