It'll work. it'll create more heat and need more watts per sq ft of coverage, but at 100w the extra heat will be irrelevant in most cases. Much bigger deal with more watts invovled.
figure 2.5sq ft of coverage over 12 hours - hang at a distance that properly focuses light on this sized area - preferably with reflective walls, too. A free klux app can help do that.
You can go maybe 3.75sq ft over 18hours and hung a bit higher for an autoflower.
so, keep the plant to an appropriate size and you'll have decent results. Do a small plant with 4 colas and can probably do 100 grams. Maybe 2-3 weeks of vege is all you should do. Depends a lot on how fast your plants grow.
as far as the vege/bloom modes. i'd use these both in flower, of course. You only need 66% of the power over 18hours as you do over 12, so there may be a little trial and error if you don't have a dimmer and only those two 'modes'. Hopefully they designed it intelligently and the vege only mode will be roughly 2/3rds of full power. Could count the diodes related to the flower switch and do some simple math to figure it out.
No problem if not.. just have to do a little trial and error with hanging distance. Watch resulitng growth. IF nodes are too tight, raise light. If nodes are too spread out, get it closer. Simple as that. Take some notes when you find that goldilocks zone with perfect growth pattern.
Hours of operation can be a 'dial' for daily amount of light provided, too. Just don't give too long of a dark cycle in vege phase, and it's another tool to fine-tune how much light you give.