I mean from those leaves its a lack of phosphorus. The die off in the middle and curl over.
I get this if the nutes or uptake is imbalanced, or if a pot is too cold usually.(is one closer to the intake vent?)
Is that one feeding on the same water as all the others? I mean its either eating way more and getting deficient, or way less and getting lock-out/overfeeding, if it is the same.
Flush it and feed 1/4 strength back in and see where its at in 3 days, looking better go back to normal feeds. looks worse maybe you actually need to feed more.