This appears to be a phosphorus deficiency, potentially caused by nutrient lockout or not enough PK!
I would check the ph of your runoff, it should be about .5-.8 lower than the water going in. I would also check the EC of your soil as well to see what kind of readings you get. Without knowing the runoff ph and EC it’s extremely hard to tell if you’re over feeding. But over feeding typically leads to burnt tips and leaves, not so much brown splotches!