Looking good so far! The PH fluctuations will cause issues like this on the leaves. PH fluctuation could cause lockout of certain nutrients, which doesn't mean add more, it means the plant can't access those nutrients. I would be very careful about adding any more nutrients, especially this early in your grow. Also, the more nutrients you have in your reservoir or watering jug, the less of an impact the PH up and PH downs will have on your reservoir. Good luck and happy growing! 💪💪