hours is part of the equation, but it's more than that. umol/s is photons per second of light in a specific range of wavelengths. photons per second, being the key. if you give a higher rate of photons you don't need as many hous of light to reach the 'maximum' your plant and evinronment allows per day.
DLI, or daily light integral, is the concept here. studies show if you give the same amount of DLi over 16 hours vs 18 hours vs 20 hours it makes no discernable difference in yield beyond normal volatility. So, if you reduce 2 hours from 18 hours, you need 1/9th (11,1%) more umol/s over those 16 hours to provide the same energy you did before.
It's proportional to hours of use and umol/s provided (technically, umol/s per meter-squared = PPFD which is what you reference to calculate DLI)
Becoming familiar with this makes communicating about lgiht in different gardens as apples to apples even though the power and area covered will vary.
35-40 DLI is going to be the max with ambient CO2. if you regulate your environment you can push 50-60 DLI. (light, co2, temperature rh, et al.. circulation is all part of environment)