Baking soda is a cheap and organic means of upping pH values. I typically always need pH down where i live and rarely pH up. But i have dropped my pH too low before and instead of wasting 10 gallons of nutrients, i just sprinkle a pinch of baking soda in there and stir it up and it's good.
Generally it's not a good idea to throw in pH down and fuck it up and need to throw in pH up to correct. You wind up with a shit soup. So pH slowly. Don't be in a hurry. And keep in mind, if you dump a large quantity of pH down into nutrient solution quickly, you may notice a cloudy film form in your solution. That's nutrients binding to one another which will cause them to be locked out, and it will fuck up your plants with deficiencies. So pH show and disperse it in various spots with a dropper rather than dumping it in one spot. Drop drop drop drop drop, mix, test. Drop drop drop drop drop, mix, test, etc. When i mix 10 gallons of nutrients, i put about 20 drops in at a time. Then i mix thoroughly and test. 20 drops will drop my pH from, for example, 6.8 to 6.6. But be careful because after mixing and testing, you will get a pH value but it's not necessarily dead accurate. Typically your pH is a little lower than what your pen reads. It's just not mixed and dispersed thoroughly. If i want a end result of 5.8, i'll mix till it reaches 6.0, then call it good.
Lately what i have been doing is mixing up my nutrients about 3 hours prior to feeding. I will pH to my liking, and then let it sit for an hour or 2, or 3. Then i re-test pH. Doing that I have found that my pH will actually be higher than where it was when i finished the pH adjustment. Maybe it's my pH pen, maybe the pH is drifting, but at any rate, if i pH to 6.0 and come back 3 hours and test and it's 6.5, i adjust it to 6.0 and then apply.
This is why I've always grown RDWC or some other water culture method, because i can drip a probe in my solution and hook it to a nutradip pH monitor and i can monitor the pH 24/7 in real time. bada bing bada boom baby haha